Liquid purification or separation – Processes – Liquid/liquid solvent or colloidal extraction or diffusing...
Reexamination Certificate
1999-04-01
2001-02-20
Fortuna, Ana (Department: 1723)
Liquid purification or separation
Processes
Liquid/liquid solvent or colloidal extraction or diffusing...
C210S090000, C210S087000, C210S096200, C210S096100, C210S097000, C210S134000, C210S805000, C210S257200, C210S195200
Reexamination Certificate
active
06190558
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to apparatus for providing potable water through the use of a reverse osmosis purification unit.
BACKGROUND OF THE INVENTION
Reverse osmosis units have been used for a number of decades to purify water for home, municipal and industrial uses. Examples of purification systems using reverse osmosis units to provide quantities of potable water suitable for home or other relatively limited uses are shown in the following patents of Donald T. Bray: U.S. Pat. Nos. 3,568,843; 3,794,172; 3,794,173 and 3,939,074. Such self-contained systems were generally designed to provide potable water on demand by being essentially permanently connected to a municipal water supply line pressure. They created a ready reservoir of purified or potable water which would be available to be dispensed to a user, either by gravity flow or by flow driven by the expansion of air compressed behind a bladder within a confined tank or the like.
Reverse osmosis membrane separation devices generally function on the basis of employing a significant fluid pressure difference between the inlet side of the membrane barrier, i.e., the feed side, and the opposite side of the membrane barrier, i.e., the product side. This pressure difference motivates the flow of fluid through the micropores of the membrane barrier while generally preventing the passage of salt and mineral solutes through the membrane. However, when such a membrane separation device is operated only intermittently, as is the practice with respect to most small scale household or domestic appliance versions of such reverse osmosis systems, a typical cyclic process occurs with every shutdown and start-up. Once the pressure difference across the membrane barrier is removed as a result of shutdown, flow through the membrane to the product side ceases. As a result, the two volumes of fluid which now occupy the void spaces on both sides of the membrane barrier are no longer subject to this pressure-driven osmotic separation effect. Consequently, the salt and mineral solutes in the liquid on the feed side of the membrane are now able to slowly pass through the membrane barrier and mix with the fluid on the product side, and the solutes generally continue to do so until equilibrated common solutions have been formed on both sides of the membrane.
When start-up again occurs so that high pressure and liquid flow are reestablished on the feed side of the membrane device, the osmotic separation process resumes; however, the residual volume of higher salt and mineral content liquid on the product side of the membrane in the purification unit will constitute the first portion of the product water stream to be discharged from the unit before a truly purified outlet stream will again be discharged from the purification unit. In most small scale or domestic appliance-type membrane separation systems, a liquid accumulation reservoir or tank is provided into which the discharge from the membrane purification unit is directed. Such a tank provides for rapid dispensing of a fairly large quantity of product liquid at the tap or other point of use, and because the tank or reservoir will be repeatedly filled to its desired capacity during periods of non-use, this arrangement permits the use of a small, economical membrane separation device having only a relatively low, direct, product flow rate. In such a system configuration, the problem of high salt and mineral content accumulating in the small volume of liquid on the product side within the purification unit during periods of shutdown becomes minimal because this small volume will be flushed into the tank or reservoir at the time of start-up where it becomes highly diluted with the very considerable volume of liquid within the product holding tank; as a result, the ultimate product remains generally acceptable.
However, there is some contamination of the product side liquid which is occurring and which, although acceptable, is still undesirable, and the search for new and improved water purification systems is an always continuing one.
SUMMARY OF THE INVENTION
The present invention provides a domestic reverse osmosis membrane separation system or the like, and a method for operating same, wherein one or more water purification units are employed which provide relatively high capacity and high performance and which are arranged so as to satisfactorily supply potable water directly to a point of use from a purification unit or units, if desired, without a product holding tank or reservoir. The design is such that significant product side contamination by salts and/or minerals during a dormant period, i.e., in the initial volume of product that is delivered upon opening the tap, is eliminated, thus providing overall improvement in the quality of potable water delivered by the unit.
Such an improved, demand-type, reverse osmosis water purification system employs a motor-driven pump which begins operation as soon as the tap is opened and continues to operate for a certain additional period following closing of the tap, during which additional period a recirculation loop is established where purified water permeating through the membrane to the product side is recirculated toward the feed side of the reverse osmosis purification unit where it mixes with a normally partially recirculating stream from the concentrate or brine side and also with a small amount of makeup water from the impure water source. Such a recirculation operation is continued until the salt and mineral level of the feed stream flowing to the purification unit has been reduced to an acceptably low level, as a result of which only insignificant contamination of the product-side liquid in the purification unit will occur as a consequence of equilibrium flow across the membrane during that shutdown period when the system is intermittently at rest, awaiting the next opening of the tap.
REFERENCES:
patent: 3568843 (1971-03-01), Brown
patent: 3774763 (1973-11-01), Yall et al.
patent: 3794172 (1974-02-01), Bray
patent: 3794173 (1974-02-01), Bray
patent: 3939074 (1976-02-01), Bray
patent: 3959146 (1976-05-01), Bray
patent: 4169789 (1979-10-01), Lerat
patent: 5000845 (1991-03-01), Solomon
patent: 5078864 (1992-01-01), Whittier
patent: 5154820 (1992-10-01), Solomon
patent: 5207916 (1993-05-01), Goheen et al.
patent: 5261792 (1993-11-01), Schoenmeyr
patent: 5460716 (1995-10-01), Wolbers
Fitch Even Tabin & Flannery
Fortuna Ana
Nimbus Water Systems, Inc.
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