Reuse method of radioactive waste salt and the apparatus...

Hazardous or toxic waste destruction or containment – Destruction or containment of radioactive waste – Chemical conversion to a stable solid for disposal

Reexamination Certificate

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C423S011000, C588S300000

Reexamination Certificate

active

07875760

ABSTRACT:
A reuse apparatus of eutectic salt waste produced in an electro refining process and a method thereof is a technology that in order to collect the eutectic salt of the eutectic salt waste, oxidizes/precipitates nuclides (rare earth and TRU) within the eutectic salt waste, an oxygen dispersing method is used to perform a layer separation into the eutectic salt layer and the precipitate layer. Then, the precipitate layer and eutectic salt layer are separated and collected, so that the eutectic salt layer is directly reused and the eutectic salt within the precipitates is reused by separating and collecting it using distillation/condensation processes. The reuse apparatus of the eutectic salt waste and a method thereof thereby increases the collecting efficiency of the eutectic salt and allows the compositions of the collected eutectic salt to have the same compositions as the eutectic salt used in the electro refining process.

REFERENCES:
patent: 5505823 (1996-04-01), Rendall
Cho, Yong-Jun, Characteristics of Oxidation Reaction of Rare-earth Chlorides for Precipitation in LiCI-KCI Molten Salt by Oxygen Sparging, Journal of Nuclear Science and Technology, vol. 43, No. 10, p. 1280-1286 (2006).
Garcia, Eduarco, Salt Distillation, Los Alamos Science, No. 26, 449 (2000).
Hee-Chul Yang et al., “Behavior of Radioactive Metal Surrogates Under Various Waste Combustion Conditions”,Journal of the Korean Nuclear Societyvol. 34, No. 1, Feb. 2002, pp. 80-89.
A.S. Wagh et al., “Stabilization of Rocky Flats Pu-contaminated ash within chemically bonded phosphate ceramics”,Journal of Nuclear Materials265 (1999) 295-307.
T. Kawata et al., “Preliminary Study on the Partitioning of Transuranium Elements in High Level Liquid Waste”,First OECD/NEA Information Exchange Meeting on Separation and Transmutation of Actinides and Fission Products, Mite, Japan, Nov. 6-9, 1990.

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