Resolution of chiral compounds using aminocyclopentadienyl...

Details Resolution of chiral compounds using aminocyclopentadienyl... Resolution of chiral compounds using aminocyclopentadienyl...

2007-01-02

2007-01-02

Barts, Samuel A (Department: 1621)

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C556S137000, C556S016000

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10507727

ABSTRACT:
A chiral compound, particularly a chiral secondary alcohol, can be efficiently resolved under a mild condition by acylation with an alkenyl acetate in the presence of a novel aminocyclopentadienyl ruthenium complex, an enzyme catalyst, and a base.

REFERENCES:
Jeong Hwan Koh, Hyun Min Jung, Mahn-Joo Kim and Jaiwook Park Enzymatic resolution of secondary alcohols coupled with ruthenium-catalyzed racemization without hydrogen mediator Tetrahedron Letters 40 (1999) 6281-6284.

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