Resist material comprising polymer of allylsilyl compound and pa

Radiation imagery chemistry: process – composition – or product th – Diazo reproduction – process – composition – or product – Composition or product which contains radiation sensitive...

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430288, 430296, 430270, 522 64, 526279, G03C 168, G03C 170, G03C 516, C08F 3008

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045645760

ABSTRACT:
A polymer having allyl groups each attached to a silicon atom serves as a resist material which is highly resistive to dry etching such as reactive sputter etching with oxygen and sensitive to electron beams, X-rays and deep UV rays. By the addition of a bis-azide compound known as a photosensitive cross-linking agent the resist material becomes sensitive also to UV and near UV rays. A very suitable polymer is obtained by polymerizing either a triallylsilane or an allylsilylstyrene or by copolymerizing an allylsilylstyrene with another ethylenic compound copolymerizable with styrene. This resist material is used in a pattern forming method of the two-layer type, in which a fine pattern is generated in a thin film of the resist material by lithography and then transferred into an underlying thick organic layer by dry etching of the thick organic layer with the resist pattern as a mask.

REFERENCES:
patent: 2538657 (1951-01-01), Rochow
patent: 3945830 (1976-03-01), Yazawa et al.
patent: 4301231 (1981-11-01), Atarashi et al.

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