Removing oxygen from a solvent extractant in an uranium recovery

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Radioactive metal

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423 8, 423321S, C01G 4300

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active

044329458

ABSTRACT:
An improvement in effecting uranium recovery from phosphoric acid solutions is provided by sparging dissolved oxygen contained in solutions and solvents used in a reductive stripping stage with an effective volume of a nonoxidizing gas before the introduction of the solutions and solvents into the stage. Effective volumes of nonoxidizing gases, selected from the group consisting of argon, carbon dioxide, carbon monoxide, helium, hydrogen, nitrogen, sulfur dioxide, and mixtures thereof, displace oxygen from the solutions and solvents thereby reduce deleterious effects of oxygen such as excessive consumption of elemental or ferrous and accumulation of complex iron phosphates or cruds.

REFERENCES:
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patent: 3214239 (1965-10-01), Hazen et al.
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patent: 4243637 (1981-01-01), Bradford et al.
patent: 4278640 (1981-07-01), Allen et al.
patent: 4323540 (1982-04-01), Sundar
Hurst et al, "Recovery of Uranium from Wet Process Phosphoric Acid", Ind. g. Chem. Process, 11, pp. 122-128 (1972).
MacCready et al, "Uranium Extraction from Florida Phosphates", Nucl. Tech., 53, pp. 344-353 (1981).

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