Removing NOx, SO 2 , and Hg from a gas stream using...

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Nitrogen or nitrogenous component

Reexamination Certificate

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Details

C423S242100, C423S243060, C423S243080, C423S243110, C204S174000, C204S177000, C588S301000, C588S320000

Reexamination Certificate

active

07048899

ABSTRACT:
A process and apparatus for removing SO2, NO, and NO2from a gas stream having the steps of oxidizing a portion of the NO in the flue gas stream to NO2, scrubbing the SO2, NO, and NO2with an ammonia, ammonium hydroxide, alkali hydroxide or carbonate scrubbing solution, regenerating the scrubbing solution with limestone, and removing any particulate matter and aerosols generated by the scrubbing step in a wet electrostatic precipitator. The process can also remove Hg by oxidizing it to oxidized Hg and removing it in the wet electrostatic precipitator. The scrubbing solution is preferably regenerated with limestone or magnesium, and results in a Group II sulfite or sulfate that can be recovered and sold, or landfilled.

REFERENCES:
patent: 3873532 (1975-03-01), Dahlstrom et al.
patent: 5316737 (1994-05-01), Skelley et al.
patent: 6136284 (2000-10-01), Hwang et al.
patent: 6203598 (2001-03-01), Hasegawa et al.
patent: WO-99/47268 (1999-09-01), None
patent: WO-01/87464 (2001-11-01), None
patent: WO-02/062453 (2002-08-01), None
Lee, etal. “The Effect of In Situ Generated Ammonia—Sulfer Aerosols on the Removal of NOx in a Wet ESP”, Aug. 20, 2001, Mega Symposium, Chicago, IL.

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