Removal of volatile acids from NMP solvent vapors with sacrifici

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D20100, C07D207267

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active

048311600

ABSTRACT:
Volatile acids present in n-methyl pyrrolidone vapor from solvent extraction processes can be reacted with sacrificial metals such as magnesium to concentrate the acid salts into a small volume of oil/NMP. Steam stripping removes NMP from the oil/NMP mixture while simultaneously springing a portion of the light carboxylic acids from their salts, the acids going with the NMP. This condensed NMP stream containing the light carboxylic acids is contacted with an ion exchange resin which removes the acids from the NMP. The purified small volume of NMP is returned to the extraction process.

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