Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group iiia metal or beryllium
Patent
1980-01-22
1981-06-23
Carter, Herbert T.
Chemistry of inorganic compounds
Treating mixture to obtain metal containing compound
Group iiia metal or beryllium
423121, 423127, 23301, 23302T, C01F 706, C01F 746
Patent
active
042750423
ABSTRACT:
Sodium oxalate in supersaturated solution in Bayer spent liquor stabilized by the presence of humic material is precipitated by the treatment with cationic sequestrants which interact with the humic material to give an insoluble product, thus removing it from solution and destabilizing the solution with respect to precipitation of sodium oxalate. Preferred cationic sequestrants are quaternary nitrogen compounds including medium or long chain alkyl groups. Precipitation of sodium oxalate can be expidited by addition of seed crystals and/or addition of sodium oxalate solution which is supersaturated at a temperature higher than that of the spent liquor.
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patent: 3899571 (1975-08-01), Yamada et al.
patent: 4038039 (1977-07-01), Carruthers
patent: 4046855 (1977-09-01), Schepers et al.
patent: 4101629 (1978-07-01), Mercier et al.
Alcan Research and Development Limited
Carter Herbert T.
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