Removal of metal ions from aqueous solution

Liquid purification or separation – Particulate material type separator – e.g. – ion exchange or...

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2105021, 502402, B01D 1508

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active

049699954

ABSTRACT:
A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat unit for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heayv metals from solution. This also results in the removal of the metals from the column in a concentrated form.

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Erwin Grill et al., "Phytochelatins: The Principal Heavy-Metal Complexing Peptides of Higher Plants," Science 230, 674-676 (Nov. 1985).
Erwin Grill et al., "Phytochelatins: A Class of Heavy-Metal-Binding Peptides from Plants, are Functionally Analogous to Metallothioneins," Proceedings of National Acacemy of Science U.S.A., 84, pp. 439-443 (1987).

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