Removal of light impurities from caprolactam by distillation wit

Distillation: processes – separatory – With disparate physical separation – Utilizing removing solid from liquid

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203 92, 203 96, 540540, B01D 314, B01D 338

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active

047675039

ABSTRACT:
This invention is a method of purifying crude caprolactam. The improved method comprises taking a portion of a process stream of crude caprolactam having low boiling impurities and distilling the stream in the presence of water by fractional distillation into an overhead containing water and low boiling impurities and bottoms of caprolactam having improved purity and low water content.
The improvement also comprises taking a low water content stream of crude caprolactam having low boiling impurities and adding water to the stream and distilling the stream by fractional distillation as described above.

REFERENCES:
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patent: 4148792 (1979-04-01), Danziger et al.
patent: 4148793 (1979-04-01), Danziger et al.
patent: 4311642 (1982-01-01), Crescentini et al.
patent: 4457807 (1984-07-01), Rulkens et al.
Weissberger, "Technique of Organic Chemistry," vol. IV, Distillation, N.Y., 1965, pp. 3 & 9.
Kirk-Othmer, "Encyclopedia of Chemical Technology", 3rd ed., vol. 18, 1807-1982, pp. 425-436.
Oldershaw, "Perforted Plate Column for Analytical Batch Distillation", vol. 13, pp. 265-268, Apr. 1941.

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