Removal of cyanide, sulfides and thiosulfate from ammonia-contai

Liquid purification or separation – Processes – Chemical treatment

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Details

210762, 210904, 210908, 210916, 210903, C02F 172

Patent

active

053605527

ABSTRACT:
Waste water chemical oxygen demand is reduced from a waste water by passing the water in the presence of an oxidizing agent through an adsorbent porous solid substrate, preferably zeolite A, zeolite X, zeolite Y, ZSM-5, erionite, or chabazite which has been partially ion exchanged with a water insoluble metal compound, copper (Cu), that cataytically facilitates oxidation of the offensive substances or the components in the waste water that increase its chemical oxygen demand, such as cyanide, sulfide, thiosulfate, sulfite, mercaptan, or disulfide. The preferred oxidizing agent is air. It is desired to develop a process for waste water treatment that is effective at reducing the concentration of the offensive substances in the waste water while minimizing the deposition of undesirable residues into the treated waste water. This process is effective in treating waste water from industrial plants, including petroleum refineries, chemical plants, pulp and paper plants, mining operations, food processing plants, and electroplating operations to reduce the concentration of the offensive substances while minimizing deposition of undesirable residues into the treated waste water.

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"Oxidation of Sulfide-Containing Refinery Wastes by Air", Chemical Abstracts Reference, Abegg et al., vol. 58, pp. 3195-3196.

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