Removal of combined organic substances from aqueous solutions

Liquid purification or separation – Processes – Treating by enzyme

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210721, 210728, 210759, 210909, 435192, 435262, C02F 154

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active

046234659

ABSTRACT:
A method is disclosed for removing organic substances, such as phenols and aromatic amines, from aqueous solutions by adding chemicals, such as peroxidase enzymes and peroxide substrates, to such solutions. A surprising discovery is that the presence of more than one organic substance greatly increases the efficiency of precipitation of substances that do not precipitate efficiently in the absence of other organic substances.

REFERENCES:
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patent: 4294703 (1981-10-01), Wilms et al.
patent: 4485016 (1984-11-01), Hopkins
Klibanov et al., "Horseradish Peroxidase for the Removal of Carcinogenic Aromatic Amines from Water", Enzyme Microb. Tech. Apr., 1981, pp. 119-122.
Saunders et al., Peroxidase Butterworths (Wash. D.C.) 1964, pp. 10-27 & 38.
Galliani et al. "Horseradish Peroxidase Catalysed Oxidation of Aromatic Tertiary Amines with H.sub.2 O.sub.2 ", J.C.S Perkin Trans I, 1978, pp. 456-460.
Baker et al., "Studies in Peroxidase Action Part 25 Stereospecificity of Peroxidase Action," Tetrahedron, 1975, pp. 1869-1872.
Danner et al. "The Oxidation of Phenol & Its Reaction Product by Horseradish Oxidase & H.sub.2 O.sub.2," Arch. Biochem. Biophys., 156, 1973, pp. 759-763.
Brignac et al. "Oxidation of Guaiacol, Serotonin, O-Cresol, P-Cresol, M-Cresol, Homovanillic Acid, & M-Tyrosine by Horseradish Peroxidase & H.sub.2 O.sub.2," Anal. Lett., 8, 1975, pp. 315-322.
Hughes et al., J.C.S, 1956, p. 3814.
Young et al., "Peroxidase Catalysed Oxidation of Naturally Occuring Phenols & Hardwood Lignins," Phytochemistry, 1973, pp. 2851-2861.

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