Removal of CO.sub.2 and/or H.sub.2 S from gases

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Carbon dioxide or hydrogen sulfide component

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Details

423226, 423229, C01B 1716, C01B 3120

Patent

active

049976303

ABSTRACT:
Gases containing CO.sub.2 and/or H.sub.2 S in a first absorption stage, at from 40.degree. to 100.degree. C., with an aqueous absorption liquid containing from 20 to 79% by weight of methyldiethanolamine, the gas obtained at the top of the first absorption stage is fed to a second absorption stage in which, it is treated at from 30.degree. to 90.degree. C. with an aqueous absorption liquid which contains from 20 to 79% by weight of methyldiethanolamine and has a lower content of CO.sub.2 and/or H.sub.2 S than the absorption liquid fed into the first absorption stage, the treated gas is taken off at the top of the second absorption stage, the aqueous absorption liquid obtained at the bottom of the second absorption stage and preladen with CO.sub.2 and/or H.sub.2 S is fed to the top of the first absorption stage, the aqueous absorption liquid obtained in the lower part of the first absorption stage and laden with CO.sub.2 and/or H.sub.2 S is let down in two or more flash stages in order to regenerate it, the final flash stage being operated under reduced pressure, a stream of absorption liquid obtained at the bottom of the final flash stage is recycled to the first absorption stage, a further stream of absorption liquid obtained at the bottom of the final and/or penultimate flash stages is fed to a stripping zone for further regeneration, and the regenerated absorption liquid obtained at the bottom of the stripping zone is recycled to the second absorption stage.

REFERENCES:
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patent: 3622267 (1971-11-01), Bartholome et al.
patent: 4146569 (1979-03-01), Giammarg36co et al.
patent: 4198378 (1980-04-01), Giammarco et al.
patent: 4336233 (1982-06-01), Appl et al.
patent: 4477420 (1984-10-01), Bauer et al.
patent: 4537753 (1985-08-01), Wagner et al.

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