Removal of basic nitrogen compounds from extracted oils by use o

Mineral oils: processes and products – Refining – With solid catalyst or absorbent

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208 14, 208254H, 208299, 208305, C10G 2500, C10G 3400

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active

048469629

ABSTRACT:
Basic nitrogen compounds (BNC) are selectively removed from solvent extracted oils by adsorption of said BNC's by solid acidic polar adsorbents. The oils are extracted using any of the common extraction solvents, such as furfural, phenol, SO.sub.2, N-methyl-2-pyrrolidone (NMP), preferably NMP. The resulting raffinate, which contains the desirable oil fraction, has the BNC's present therein removed by adsorption thereof onto an adsorbent, characterized as being a solid, polar acidic adsorbent, exemplified by silica-alumina, a high alumina base amorphous cracking catalyst (such as manufactured by Ketjen/Akzo) and crystalline zeolite (such as H-Y zeolites) are effective adsorbents. The adsorbents may additionally contain fluorine or may contain up to 30 weight percent water. The adsorbents are regenerated by either purging with hydrogen at elevated temperature and pressure, or by washing the BNC saturated adsorbent with extraction process extraction solvent, such as NMP.
Extracted oil raffinate treated with the adsorbent to remove BNC exhibit superior uninhibited oxidation stability as compared to untreated conventional hydrofined oil.

REFERENCES:
patent: 1997938 (1935-04-01), Loomes
patent: 2195659 (1940-04-01), Shoemaker
patent: 2273846 (1942-02-01), Dunmere
patent: 2316005 (1943-04-01), Lachle
patent: 2352064 (1944-06-01), Zerbe
patent: 2375696 (1945-05-01), Strickland
patent: 2384315 (1945-09-01), Kuhl
patent: 2647858 (1953-08-01), Weisz
patent: 2708519 (1955-05-01), Novak
patent: 2744053 (1956-05-01), Kay et al.
patent: 2769751 (1956-11-01), Paull
patent: 2908639 (1959-10-01), Carter et al.
patent: 2919251 (1959-12-01), Shuman
patent: 2926135 (1960-02-01), Engel et al.
patent: 2949421 (1960-08-01), Mills
patent: 2951036 (1960-08-01), Bodkin
patent: 2954338 (1960-09-01), Carmody
patent: 2984620 (1961-05-01), Fleck et al.
patent: 3189539 (1965-06-01), Sieg
patent: 3201344 (1965-08-01), Broughton
patent: 3224955 (1965-12-01), Anderson
patent: 3238123 (1966-03-01), Vourhies et al.
patent: 3239455 (1966-03-01), Lickus
patent: 3243366 (1966-03-01), Kimberlin et al.
patent: 3331770 (1967-07-01), Cockerham
patent: 3462358 (1969-08-01), Mills et al.
patent: 3551324 (1970-12-01), Lillard
patent: 3654128 (1972-04-01), Woodle
patent: 3705850 (1972-12-01), Wolk
patent: 3732154 (1973-05-01), Mills et al.
patent: 3755152 (1973-08-01), Gulick
patent: 3830730 (1974-08-01), Meud et al.
patent: 3849298 (1974-11-01), Funakubo et al.
patent: 3901792 (1975-08-01), Wolk
patent: 3920540 (1975-11-01), McCoy et al.
patent: 3922217 (1975-11-01), Cohen et al.
patent: 3926783 (1975-12-01), Wolk
patent: 4008148 (1977-02-01), Masshugu et al.
patent: 4081352 (1978-03-01), West et al.
patent: 4090951 (1978-05-01), Smith
patent: 4110196 (1978-08-01), Bosniaek et al.
patent: 4120782 (1978-10-01), Aucleh et al.
patent: 4137154 (1979-01-01), Audeh
patent: 4152249 (1979-05-01), Arvillon et al.
patent: 4269694 (1981-05-01), Holland et al.
patent: 4404118 (1983-09-01), Herskovits
patent: 4419219 (1983-12-01), Long et al.
patent: 4422926 (1983-12-01), Gould et al.
patent: 4423278 (1983-12-01), Yang et al.
patent: 4424114 (1984-01-01), Murrell et al.
patent: 4455444 (1984-06-01), Kulprathipanja et al.
patent: 4469805 (1984-09-01), Kotke, Jr. et al.
patent: 4487688 (1984-12-01), Dessau
patent: 4622130 (1986-11-01), Stem
"Removal of Nitrogen Compounds From Lubricating Oils", Ind. Eng. Chem., Prod. Res. Dev. 22 (2), pp. 276-279, Jun. 1983.
"Silicalite, a new hydrophobic crystalline silica molecular sieve" Flanigen et al., Nature, vol. 271, 9, Feb. 1978, pp. 512-516.

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