Reinforced polyvinyl alcohol hydrogels containing uniformly disp

Plastic and nonmetallic article shaping or treating: processes – With step of cooling to a temperature of zero degrees c. or...

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264196, 264345, 264349, 264185, 264203, 524503, 428357, 428359, 428373, 428374, B29C 3500, B29C 3502, B29C 3516

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active

054220505

ABSTRACT:
This invention provides reinforced composite structures consisting essentially of a matrix and a dispersed phase, where the matrix is a hydrogel containing water and a solubilized vinyl alcohol homopolymer, the dispersed phase contains a plurality of uniformly distributed acicular regions consisting of fibrils formed from a highly oriented crystalline vinyl alcohol polymer, where the diameter of the said fibrils is less than 1 millimeter, the aspect ratio of the fibrils is from 2:1 to 1000:1, and where the composite is characterized by a gradual transition in the degree of crystallinity at the interfaces between the matrix and the fibrils.

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"Kobunshi Kako" 39(6) 304-310 (1990) (CA114(16) :144304x).
"Kobunshi Ronbunshi" 46 (11) 673-80 (1989) (CA112 (12):99763s).
"J. Controlled Release" 18(2), 95-100; (CA116(16) : 158711f).
R. Ofstead et al. in Adv. Chem. Ser., 223 (Polym. Aqueous Media), 61-72 (CA112(6) :42493z).
"Kobunshi Ronbunshu" 47(12), 1001-4 (1990) (CA114(8) : 63302t).

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