Reinforced fluoropolymer composite

Stock material or miscellaneous articles – Structurally defined web or sheet – Including grain – strips – or filamentary elements in...

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428220, 428245, 428251, 428252, 428262, 428265, 428267, 428268, 428286, 428287, 428378, 428392, 428421, 428422, B32B 704, B32B 2712

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active

052309371

ABSTRACT:
A novel composite comprises a substrate having a coating matrix including an initial layer of a perfluoropolymer and an overcoat comprising a fluoroelastomer, a fluoroplastic, a fluoroelastomer/fluoroplastic blend, or a combination thereof. The perfluoropolymer in the initial layer may be a perfluoroplastic, a perfluoroelastomer, or blends thereof. In a separate embodiment, the novel composite includes a substrate coated solely with one or more layers of perfluoroelastomer alone or as a blend with a perfluoroplastic. Where the substrate is not susceptible to hydrogen fluoride corrosion, the composite may include solely one or more layers of a blend of a fluoroelastomer and a hydrogen-containing perfluoroplastic. Cross-linking accelerators may be used to cross-link one or more of the resins contained in the coating layers. Each composite may be top-coated with a layer or layers of a fluoroplastic, fluoroelastomer, and/or a blend thereof. The composite is flexible, exhibits good matrix cohesion and possesses substantial adhesion of the matrix to the material acting as the reinforcement or substrate. A method for making such a composite comprises the unique deployment of a perfluoropolymer directly onto the substrate in a relatively small amount sufficient to protect the substrate from chemical corrosion without impairing flexibility, followed by the application of the overcoat layer.

REFERENCES:
patent: 3790403 (1974-02-01), Ribbans, III
patent: 3993827 (1976-11-01), Dukert et al.
patent: 4165404 (1979-08-01), Quehl
patent: 4252859 (1981-02-01), Concannon et al.
patent: 4299869 (1981-11-01), Casson et al.
patent: 4450197 (1984-05-01), Hager et al.
patent: 4469744 (1984-09-01), Grot et al.
patent: 4610918 (1986-09-01), Effenberger et al.
patent: 4770927 (1988-09-01), Effenberger et al.
Bulletin #28, Armalon.RTM. TT-9001, "Here's another new development . . . from the Industrial Products Division at Dupont", Nov. 1, 1971.
Industrial fabrics, Fairprene.RTM., Corfam.RTM., Armalon.RTM., Dupont, 1969.

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