Regeneration procedure for iridium-containing catalyst

Mineral oils: processes and products – Chemical conversion of hydrocarbons – Reforming

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252415, C10G 3508, B01J 2396

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active

039376605

ABSTRACT:
Supported iridium-containing hydrocarbon conversion catalysts which are at least partially deactivated due to the deposition of carbonaceous residues thereon during contact with hydrocarbons are regenerated by (1) contacting the catalyst with oxygen to burn at least a portion of the carbonaceous residues from the catalyst, (2) contacting the carbonaceous residue-depleted catalyst with hydrogen at an elevated temperature to convert a substantial portion of the iridium present in the catalyst to its metallic form, (3) contacting the reduced catalyst with an elemental halogen-containing gas at a temperature of at least about 300.degree.C., and (4) repeating steps (2) and (3), in sequence, at least one additional time to thereby redisperse the iridium catalyst component to a highly active, high surface area state.

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