Regeneration of spent hydrodesulfurization catalysts employing p

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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208216R, 252411R, 252412, 252414, 423 68, 423150, B01J 2394, B01J 2392, B01J 2120, C10G 2302

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active

042724007

ABSTRACT:
The removal of metals, especially vanadium, from spent hydrofining catalyst is accomplished by a two-step process. Treatment with a gaseous sulfur-containing reagent brings the metals to the surface of the catalyst and converts them to sulfides, which are then efficiently removed by contact with a heteropoly acid such as molybdophosphoric acid. Treatment of deactivated hydrodesulfurization catalysts such as Co-Mo supported on alumina by this process results in substantially complete regeneration of catalytic activity.

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patent: 4083771 (1978-04-01), O'Hara

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