Refractory metal reinforced MoSi.sub.2 /SiC composite with match

Powder metallurgy processes – Powder metallurgy processes with heating or sintering – Metal and nonmetal in final product

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419 17, 419 23, 419 24, 419 38, 417 48, 417 49, 75230, 75236, B22F 312

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active

053405315

ABSTRACT:
A method for producing a substantially silica-free composition of matter comprising a matrix of MoSi.sub.2 having SiC dispersed therein, the matrix being reinforced with a particulate ductile refractory metal, the method comprising providing a composite of the particulate ductile refractory metal and a substantially silica-free composite mechanical alloy powder comprising MoSi.sub.2 and SiC having a composition in that segment of the ternary diagram of FIG. 1 designated A, and consolidating the composite of particulate ductile refractory metal and mechanical alloy powder; the coefficient of thermal expansion of the MoSi.sub.2 matrix having SiC dispersed therein being substantially equivalent to that of the particulate ductile refractory metal. The composition of matter formed by the method and an article of manufacture comprising the same are also disclosed.

REFERENCES:
patent: 4543345 (1985-09-01), Wei
patent: 4927792 (1990-05-01), Petrovic et al.
patent: 5000896 (1991-03-01), Petrovic et al.
J. Mater. Res., vol. 8, No. 6, Jayashankar et al, "Tailored MoSi.sub.2 /SiC Composites By Mechanical Alloying," p. 1428 (after Jun. 1, 1993).
J. Am. Ceram. Soc., vol. 74, Maloy et al, "Carbon Additions To Molybdenum Disilicide: Improved High-Temperature Mechanical Properties," p. 2704 (1991).
Scripta Metall., vol. 27, Hardwick et al, "Reaction Synthesis of MoSi.sub.2 From High Purity Elemental Powders," p. 391 (1992).
Mater. Sci. Eng., vol. A155, Schwarz et al, "Synthesis of Molybdenum Disilicide By Mechanical Alloying," p. 75 (1992).
Scripta Metall., vol. 26, Jayashankar et al, "In-Situ Reinforced MoSi.sub.2 Composites By Mechanical Alloying," p. 1245 (1992).

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