Reforming process with catalyst pretreatment

Mineral oils: processes and products – Chemical conversion of hydrocarbons – Reforming

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Details

208134, 208135, 208138, 502 85, 502521, C10G 35085

Patent

active

059140283

ABSTRACT:
A catalytic reforming process using a halided zeolite catalyst containing platinum in a metal-coated reactor system where, prior to catalyst loading and reforming, halide acid is removed from the catalyst. The process comprises providing a reforming reactor system having a metal coating; providing a halided zeolite catalyst containing platinum prepared by a method which includes removing volatile halide acid; loading said catalyst into said reactor system; and catalytically reforming hydrocarbons to aromatics, wherein metal from the metal-coated reactor system does not deactivate the catalyst. The coating metal preferably comprises tin and the zeolite catalyst is preferably a platinum L-zeolite catalyst. The invention is also a method for reducing catalyst contamination from a metal which was used to coat a reactor system. The method comprises pretreating a halided catalyst with hydrogen to remove volatile halide acid. The resulting catalyst is then loaded into a metal-coated reactor system and hydrocarbons are converted.

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