Reductive coupling of nitrobenzene or nitrobenzenes substituted

Organic compounds -- part of the class 532-570 series – Organic compounds – Azoxy

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534585, C07C24508, C07C29108

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059170239

ABSTRACT:
Nitrobenzene or a nitrobenzene substituted on the nucleus is subjected to reductive coupling to give the corresponding azobenzene and azoxybenzene under heterogeneous catalysis with substantial avoidance of overreduction to aniline derivatives by means of a redox catalyst in its reduced or partly reduced form, the redox catalyst containing at least one active metal component capable of a change of oxidation state.

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