Reduction of sulfonic acid to thiol

Details Reduction of sulfonic acid to thiol Reduction of sulfonic acid to thiol

1987-09-17

1988-08-30

Ceperley, Mary E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Sulfur containing

568 69, C07C14800

Patent

active

047678844

ABSTRACT:
A sulfonic acid is reduced to a thiol by heating the acid under carbon monoxide pressure in the presence of a rhodium carbonyl catalyst.

REFERENCES:
Kirk-Othmer Encyclopedia of Chemical Technology, Third Edition, vol. 18, pp. 265 and 275 (1982); Supplement volume pp. 19 and 41 (1984).
J. March, Advanced Organic Chemistry, Third Edition, p. 1076 (1985).
L. Numata et al, Tetrahedron Letters, vol. 21, pp. 1235-1238 (1980).

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