Reduction of organic halides in alkylate gasoline

Chemistry of hydrocarbon compounds – Saturated compound synthesis – By condensation of a paraffin molecule with an olefin-acting...

Reexamination Certificate

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C585S722000, C585S727000, C585S728000

Reexamination Certificate

active

07902419

ABSTRACT:
An alkylation process comprising contacting a first hydrocarbon feed comprising at least one olefin having from 2 to 6 carbon atoms and a second hydrocarbon feed comprising at least one isoparaffin having from 3 to 6 carbon atoms with a halide-based acidic ionic liquid catalyst under alkylation conditions to produce an alkylate containing an organic halide and contacting at least a portion of the alkylate with a hydrotreating catalyst in the presence of hydrogen under hydrotreating conditions to reduce the concentration of the organic halide in the alkylate is disclosed.

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patent: 2004/0077914 (2004-04-01), Zavilla et al.
Adavis et al., Stereoselective hydrogenation reations in chloroaluminate (III) ionic liquids: a new method for the reduction of aromatic compounds, Chem Commun., 1999, pp. 1043-1044.
Chauvin, et al., Alkylation of isobutene with 2-butene using 1-butyl-3methylimidazolium chloride-aluminium chloride molten salts as catalysts, 1994, pp. 155-165, Journal of Molecular Catalysis 92.

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