Reduction of nitrogen-based pollutants through the use of urea s

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Nitrogen or nitrogenous component

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C01B 2100

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active

047190922

ABSTRACT:
Disclosed is a process for maintaining low effluent ammonia contents while reducing nitrogen oxides in an effluent from the combustion of a carbonaceous fuel under oxygen-rich conditions which minimize the production of carbon-based pollutants. An aqueous solution of urea and an oxygenated hydrocarbon is injected into an effluent at a temperature above 1600.degree. F., and preferably above 2000.degree. F. The oxygenated hydrocarbon will be employed at a level effective to reduce the levels of free ammonia in the effluent. This is important when burning fuels containing significant sulfur contents because the free ammonia tends to react with the sulfur compounds to produce solid ammonium sulfate and/or bisulfate which can decrease boiler efficiency.

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patent: 4507269 (1985-03-01), Dean et al.
patent: 4624840 (1986-11-01), Dean et al.

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