Reduction of acrylic acid in the production of maleic anhydride

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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C549S260000

Reexamination Certificate

active

07619099

ABSTRACT:
An improved process for the production of maleic anhydride by the catalytic oxidation of n-butane. Maleic anhydride is produced by reacting n-butane gas with oxygen gas or an oxygen-containing gas, in the presence of a vanadium phosphorus oxide catalyst. A trialkyl phosphite or trialkyl phosphate component is continuously added to the gases in an amount of from about 0.5 ppm to about 4 ppm by weight of elemental phosphorus in the trialkyl phosphate or trialkyl phosphite component. Heat is applied to the gases at a temperature of from about 400° C. to about 440° C. while maintaining a maximum temperature of gases present in the reaction of about 480° C. A simultaneous conversion of n-butane to maleic anhydride of about 84% or more and a conversion of n-butane to by-product acrylic acid of about 1.5% or less is achieved.

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patent: 5185455 (1993-02-01), Ebner
patent: 5360916 (1994-11-01), Padia et al.
patent: 5945368 (1999-08-01), Felthouse et al.
patent: 6194587 (2001-02-01), Doshi
patent: 6858561 (2005-02-01), Bortinger et al.

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