Chemistry of inorganic compounds – Sulfur or compound thereof – Elemental sulfur
Patent
1976-09-24
1980-06-03
Peters, G. O.
Chemistry of inorganic compounds
Sulfur or compound thereof
Elemental sulfur
423226, 423227, C01B 1704
Patent
active
042061946
ABSTRACT:
A process for treating a hydrogen sulfide-containing hydrogenated Claus process tail gas to convert the hydrogen sulfide to elemental sulfur in which said gas is contacted with an aqueous alkaline solution containing a water-soluble metal vanadate, a water-soluble anthraquinone disulfonate, and a water-soluble phenolic complexing agent or a water-soluble carboxylic complexing agent, to yield an effluent gas of reduced sulfur content. The solution is thereafter regenerated by contact with an oxygen-containing gas, elemental sulfur is recovered from the solution, and the regenerated solution is recycled to the gas-contacting step. The complexing agent contained in the solution reduces the chemical consumption of the anthraquinone disulfonate.
REFERENCES:
patent: 1792097 (1931-02-01), Jacobson
patent: 3642448 (1972-02-01), Beavon
patent: 3928535 (1975-12-01), Schulz
Fenton Donald M.
Vaell Raoul P.
Farrell Daniel R.
Peters G. O.
Sandford Dean
Union Oil Company of California
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