Reducing corrosion in reactors used for the synthesis of chromiu

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

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21 25R, 423 58, 252387, C23F 1118

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active

040849368

ABSTRACT:
In order to reduce corrosion of the inside walls of a reactor made of iron or an iron alloy and used for the synthesis of chromium dioxide by hydrothermal conversion of chromium(VI) oxide with chromium oxides of lower valency, lead or bismuth is added at those points of the reactor at which an aqueous phase occurs during conversion and which do not contact the chromium oxides to be converted. The lead or bismuth may be used in metallic form or in the form of their oxides, hydroxides or salts.

REFERENCES:
patent: 3087778 (1963-04-01), Negra et al.
patent: 3493328 (1970-02-01), Nieuwenhuis
patent: 3615264 (1971-10-01), Berry et al.

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