Chemistry: electrical current producing apparatus – product – and – Having earth feature
Patent
1996-09-11
1997-11-04
Gorgos, Kathryn L.
Chemistry: electrical current producing apparatus, product, and
Having earth feature
429 44, 204290R, 204292, H01M 486
Patent
active
056838298
ABSTRACT:
The invention refers to a fuel cell electrode for oxidation preferably methanol or methanol reformate in a fuel cell with acid electrolytes. The electrode material comprises of a) carbons modified by the chemisorption or covalent attachment of metallocomplexes, over which a noble metal catalyst such as platinum is deposited, b) carbon-noble metal systems mixed with metallocomplexes, and c) mixtures of noble metal blacks and metallocomplexes. An improvement of 100-200 mV is seen over controls using platinum alone in full tests using methanol and oxygen or air. The advantages of using the disclosed promoters is the use of low loaded (20% Pt on carbon) electrodes rather than pure noble metal or alloy blacks.
REFERENCES:
patent: 3291753 (1966-12-01), Thompson
patent: 4407905 (1983-10-01), Takeuchi et al.
patent: 4769296 (1988-09-01), Sterzel
patent: 4828941 (1989-05-01), Sterzel
patent: 5171644 (1992-12-01), Tsou et al.
patent: 5223102 (1993-06-01), Fedkiw et al.
Butte et al, The Synthesis of Some Pyridylpyridazines and Pyrimidines Sep. 1961, pp. 4690-4692.
Geldard et al, The Organic Chemistry of a New Weak Field Tridentate Chelating Agent. 3,5-D1(2-Pyridyl)-1,2,4-Triazole Jan. 1965, pp. 318-319.
Rillema et al, Multimetallic Ruthenium(II) Complexes Based on Biimidazole and Bibenzimidazole: Effect of Dianionic Bridging Ligands on Redox and Spectral Properties, vol. 29 #2, 1990, 167-173, Inorganic Chemistry No month available.
Fieselmann et al, Synthesis, Electron Paramagnetic Resonance, and Magnetic Studies of Binuclear BIS(N.sup.5 -Cyclopentadienyl) Titanium(III) Compounds with Bridging Pyrazolate, Biimidazolate, and Bibenzimidazolate Anions, vol. 8, 1978, pp. 2078-2084, Inorganic Chemistry No month available.
Che et al, Ruthenium(III) Tertiary Amine Complexes vol. 24, 1985, pp. 1061-1062, Inorganic Chemistry No month available.
Che et al, A High Valent Ruthenium(VI) Dioxo Cation of 1,4,8,11-Tetramethyl-1,4,8,11-Tetraazacyclotetradecane, vol. 24, 1985, pp. 1797-1800, Inorganic Chemistry No month available.
Watanabe et al, Applications of the Gas Diffusion Electrode to a Backward Feed and Exhaust (BFE) Type Methanol Anode, vol. 199, 1986, pp. 311-322, J. Electroanal Chemistry No month available.
Braunstein et al, Spectroscopic and Electrochemical Properties of the Dimer Tetrakis (2,2'-Bibyridine) (U-2,3-Bis(2-Pyridyl)Pyrazine) Diruthenium(II) and its Monomeric Analogue vol. 23, 1984, pp. 857-864, Inorganic Chemistry No month available.
Giner, Electrochemical Reduction of CO.sub.2 on Platinum Electrodes in Acid Solutions vol. 8, 1963, pp. 857-865, Electrochimica Acta No month available.
Watanabe et al, A Gas Diffusion Electrode for Oxygen Reduction Working at 100% Utilization of Catalysts Clusters vol. 183, 1985, pp. 391-394, J. Electroanal Chemistry No month available.
Jahnke et al, "Organic Dyestuffs As Catalysts For Fuel Cells", Topics In Current Chemistry, 61, 133 (1970) No month available.
Gorgos Kathryn L.
Mayekar Kishor
LandOfFree
Redox promoters for methonol fuel cells does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Redox promoters for methonol fuel cells, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Redox promoters for methonol fuel cells will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-1831909