Redox-active centers

Details Redox-active centers Redox-active centers

1989-04-26

1991-06-04

Prescott, Arthur C.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556136, 556138, 556140, C07C 1502, C07C 1100, C07C 1500

Patent

active

050215922

ABSTRACT:
A polymetallocene macrocycle which comprises a ring of alternating in-chain aromatic residues and in-chain alkylene units and which bears four or more transition metal complexes or metallocenyl groups. Such macrocycles are redox-active hydrophobic host molecules potentially useful as electron transfer mediators, for chemical sensor design, as redox catalysts or as Second Harmonic Generator material.

REFERENCES:
patent: 3644455 (1972-02-01), Onsager
patent: 4767873 (1988-08-01), Katz et al.
patent: 4888032 (1989-12-01), Busch

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