Recycling polyolefins coated with chlorine-containing polymer

Plastic and nonmetallic article shaping or treating: processes – Carbonizing to form article – Agglomeration or accretion

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134 84, 264 37, 264140, 264349, 264DIG69, 427336, 427444, 521 46, 425205, B29B 1700

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052864243

ABSTRACT:
Recycling polyolefin material, e.g. biaxially oriented polypropylene film, coated with a chlorine-containing polymer, such as polyvinylidene chloride homopolymer and/or copolymer, and having a primer therebetween. First, a caustic solution is formulated containing from about 0.1 wt. % to about 50 wt. % caustic, and from about 0.05 wt. % to about 1.0 wt. % of a wetting agent. The formulated caustic solution is heated to a temperature from about 25.degree. C. to about 140.degree. C. The polyolefin material is soaked in the heated caustic solution until the material is separable from the chlorine-containing polymer. After separating the polyolefin material from the chlorine-containing polymer, the material is reprocessed into desired product by extrusion, molding or other product forming process.

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patent: 4073661 (1978-02-01), Buzga et al.
patent: 4098996 (1978-07-01), Ryan et al.
patent: 4138534 (1979-02-01), Tedesco
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patent: 4643861 (1987-02-01), Hager
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patent: 4877821 (1989-10-01), Hall et al.
patent: 5066434 (1991-11-01), Liu et al.
Polymer Monographs, vol. 5; Polyvinylidene Chloride; Ritchie A. Wessling; Gordon and Breach Science Publishers: 1977; pp. 146-151.

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