Recycling of CdTe photovoltaic waste

Specialized metallurgical processes – compositions for use therei – Processes – Free metal or alloy reductant contains magnesium

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75711, C21B 1500

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active

058976850

ABSTRACT:
A method for extracting and reclaiming metals from scrap CdTe photovoltaic cells and manufacturing waste by leaching the metals in dilute nitric acid, leaching the waste with a leaching solution comprising nitric acid and water, skimming any plastic material from the top of the leaching solution, separating the glass substrate from the liquid leachate, adding a calcium containing base to the leachate to precipitate Cd and Te, separating the precipitated Cd and Te from the leachate, and recovering the calcium-containing base.

REFERENCES:
patent: 5431713 (1995-07-01), Meyerson et al.
patent: 5779877 (1998-07-01), Drinkard, Jr. et al.
Copper, Chapter 8, Electrolytic Refining pp. 165-222, Eichrodt et al, Dec. 1954.
Tolley et al, Report of Investigations-9588 "Recovering Cadmium and Tellurium From Thin Film Photovoltaic Device Scrap", US Bureau of Mines, Dec. 1995.

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