Recrystallization of activated rare-earth oxyhalide phosphors

Chemistry: physical processes – Physical processes – Crystallization

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2523014H, C09K 1146

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active

043114873

ABSTRACT:
A method for the recrystallization of activated rare-earth oxyhalide phosphors is disclosed. The method comprises recrystallizing the phosphor by firing a phosphor-flux mixture in an inert atmosphere. The phosphor-flux is substantially homogeneous and the flux contains substantially dehydrated magnesium halide. One particularly preferred phosphor made by the method is a lanthanum oxychloride phosphor coactivated with bismuth and ytterbium. This phosphor made by the present method has high speed and low afterglow.

REFERENCES:
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patent: 3607770 (1971-09-01), Rabatin
patent: 3667921 (1972-06-01), Grodkiewicz et al.
patent: 4068129 (1978-01-01), Rabatin
patent: 4080306 (1978-03-01), Ferretti
Matsubara, "Mat. Res. Bull.", vol. 7, pp. 963-969, 1972.
Mazza et al., "Gazzetta-Chimica Italiana", 70, pp. 57-72, 1940.

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