Recovery of vanadium and copper catalyst metals using ketones

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group ib metal

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423 34, 423 64, 423 65, 423 68, 260531R, 260537P, C01G 300, C01G 3100, C07C 5514

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039832082

ABSTRACT:
An aqueous nitric acid solution derived from an adipic acid process containing copper and vanadium catalyst values and alkyl dicarboxylic acids is treated to remove the nitric acid and water therefrom so as to obtain a substantially dry, molten-type residue. This residue is mixed with a dialkyl ketone solvent which dissolves the dicarboxylic acids and leaves the catalyst metal values as solids.

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patent: 3290369 (1966-12-01), Bonfield et al.
patent: 3459512 (1969-08-01), Connolly et al.
patent: 3818081 (1974-06-01), Adamek

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