Recovery of tertiary butyl hydroperoxide and tertiary butyl alco

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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549541, 5689098, 568913, C07D30132, C07D30819

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active

049772856

ABSTRACT:
A heavy distillation fraction comprising tertiary butyl hydroperoxide, tertiary butyl alcohol, impurities and dissolved molybdenum catalyst resulting from the removel of propylene, propylene oxide and tertiary butyl alcohol from an epoxidation reaction product is mixed with about 5 to about 10 wt. %, based on the weight of the heavy liquid distilation fraction, of a lower aliphatic alcohol containing from 1 to 3 carbon atoms to provide a charge mixture, and the charge mixture is:

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patent: 3881996 (1975-05-01), Schmidt
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patent: 4140588 (1979-02-01), Schmidt
patent: 4455283 (1984-06-01), Sweed
patent: 4705903 (1987-11-01), Sanderson
patent: 4709482 (1987-11-01), Sanderson

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