Recovery of sodium aluminate from high-silica aluminous material

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group iiia metal or beryllium

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423122, 423131, 23301, 23302R, 23305A, 423600, C01F 706

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active

039989275

ABSTRACT:
An improved process is provided for the recovery of sodium aluminate crystallized from a digest of caustic and lime with high-silica aluminous materials. The digest solution is concentrated by evaporation and then seeded with Na.sub.2 Al.sub.2 O.sub.4.2.5H.sub.2 O crystals to crystallize alumina from the solution as Na.sub.2 Al.sub.2 O.sub.4.2.5H.sub.2 O. The crystals are then separated from the mother liquor solution by filtration or centrifugation. The crystals are then washed with a solution having a lower caustic content than the mother liquor and an alumina concentration of about 50 grams per liter to remove any mother liquor remaining on the crystals. The sodium aluminate crystals are used as a feed for a subsequent Bayer processing step.

REFERENCES:
Ponomarev et al., "Tavetuge Metally", 1957, pp. 45-51.

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