Recovery of nitrated compounds using solvent extraction and dist

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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203 11, 203 91, 260705, C07C 7702, B01D 310

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041675215

ABSTRACT:
A method for separating an aqueous solution which contains minor amounts of nitrated esters which are only slightly soluble in water is provided. Separation of the nitrated esters, which include ethylene glycol dinitrate and nitroglycerin, is effected by contacting the aqueous solution with an organic phase of ethylene glycol dinitrate for a period of time sufficient to allow extraction of the nitroglycerin in solution into the ethylene glycol dinitrate phase. The organic ethylene glycol dinitrate phase is then separated from the aqueous solution, and the latter is distilled at a temperature of from about 50 degrees F. to about 200 degrees F. at a lower than atmospheric pressure. Upon completion of the separation process water, which is substantially free of nitrated esters, is suitable for discharge and return to a natural environment.

REFERENCES:
patent: 262913 (1882-08-01), Armandy
patent: 3620928 (1971-11-01), Miserlis
patent: 3721610 (1973-03-01), Chaintron
Urbanski, Chemistry and Technology of Explosives, vol. II, Pergamon Press, New York, 1965, pp. 37, 82, 83 and 142 to 145.

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