Recovery of molybdenum as an aqueous solution from spent catalys

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group vib metal

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423 53, 252414, 252420, C01G 3900

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043158960

ABSTRACT:
The process of separating components of a crude reaction mixture obtained from a molybdenum-catalyzed hydroperoxide epoxidation of an olefin wherein the product epoxide and an alcohol corresponding to the hydroperoxide used are removed from the reaction mixture leaving a spent catalyst solution and subjecting the spent catalyst solution to a liquid-to-liquid solvent extraction to separate dissolved molybdenum values is improved by solvent extracting the spent catalyst solution with an extracting medium consisting essentially of water and a water immiscible organic solvent to form a two phase system and then separating the molybdenum-rich aqueous phase extract from the organic phase extract. The molybdenum-rich aqueous phase extract may be treated to recover the molybdenum as a solid or the extract may be treated to obtain an active molybdenum catalyst suitable for reuse as a catalyst in a hydroperoxide epoxidation reation.

REFERENCES:
patent: 3763303 (1973-10-01), Khuri et al.
patent: 3931044 (1976-01-01), Maurin

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