Recovery of isoprene from a C.sub.5 -hydrocarbon mixture

Distillation: processes – separatory – With chemical reaction – Including step of adding catalyst or reacting material

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203 50, 203 74, 203 78, 203DIG19, 203 99, 585810, 585865, B01D 340

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046473440

ABSTRACT:
Isoprene is recovered from a C.sub.5 -hydrocarbon mixture containing isoprene, penta-1,3-diene and cyclopentadiene by separating the said mixture by liquid-liquid extraction or extractive distillation with the aid of a selective solvent, in combination with a distillation upstream or downstream from the liquid-liquid extraction or extractive distillation, by a method in which a stream containing penta-1,3-diene and cyclopentadiene is separated off in the upstream or downstream distillation and is catalytically hydrogenated, and the hydrogenated stream is fed to the upper part of the liquid-liquid extraction or extractive distillation.

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