Recovery of hydrogen fluoride from metallic fluoride salts

Chemistry of inorganic compounds – Halogen or compound thereof – Hydrogen halide

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203 12, 203 74, 203 76, 423488, C01B 719

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042332818

ABSTRACT:
Anhydrous hydrogen fluoride of high purity can be recovered from metallic fluoride salts containing phosphate values by digesting the metallic salts in an aqueous solution in a humid atmosphere at a sufficiently high temperature to release a gas containing hydrogen fluoride and negligible amount of P.sub.2 O.sub.5. The released gas is rectified in a rectification operation which includes a rectification zone in which the rectification occurs in the presence of sulfuric acid.

REFERENCES:
patent: 2753253 (1956-07-01), Hollingsworth
patent: 2759795 (1956-08-01), Archer
patent: 3091513 (1963-05-01), Parish
patent: 3167391 (1965-01-01), Swinehart
patent: 3257167 (1966-06-01), Mohr et al.
patent: 3615195 (1971-10-01), Bierman
patent: 3825655 (1974-07-01), Eipeltaner et al.
patent: 3935298 (1976-01-01), Sugahara et al.
Lecassie et al. "Sulfuric Acid Extractive Distillation Process for Recovery of Anhydrous Hydrofluoric Acid from By-Product Aqueous Hydrofluoric Acid" A.E.C., Technical Information Service NY02048, Declassified 1955.

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