Chemistry of inorganic compounds – Halogen or compound thereof – Hydrogen halide
Patent
1978-06-09
1980-11-11
Hearn, Brian E.
Chemistry of inorganic compounds
Halogen or compound thereof
Hydrogen halide
203 12, 203 74, 203 76, 423488, C01B 719
Patent
active
042332818
ABSTRACT:
Anhydrous hydrogen fluoride of high purity can be recovered from metallic fluoride salts containing phosphate values by digesting the metallic salts in an aqueous solution in a humid atmosphere at a sufficiently high temperature to release a gas containing hydrogen fluoride and negligible amount of P.sub.2 O.sub.5. The released gas is rectified in a rectification operation which includes a rectification zone in which the rectification occurs in the presence of sulfuric acid.
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Lecassie et al. "Sulfuric Acid Extractive Distillation Process for Recovery of Anhydrous Hydrofluoric Acid from By-Product Aqueous Hydrofluoric Acid" A.E.C., Technical Information Service NY02048, Declassified 1955.
Hirko Ronald J.
Mills Harold E.
Bisson Barry A.
Hearn Brian E.
Occidental Chemical Company
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