Recovery of hydrofluoric acid from fluosilicic acid

Chemistry of inorganic compounds – Silicon or compound thereof – Oxygen containing

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423341, 423483, 423484, 423490, 423551, C01B 3312, C01B 722, C01D 302

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042985862

ABSTRACT:
Hydrofluoric acid is recovered from fluosilicic acid by reacting fluosilicic acid with sodium sulfate to form sodium fluosilicate. The sodium fluosilicate is reacted with a sodium-containing compound to form an alkaline aqueous slurry comprising silica and dissolved sodium fluoride. The reaction occurs under such conditions that the slurry contains precipitated amorphous silica. The precipitated amorphous silica is separated from the alkaline aqueous slurry leaving an aqueous solution of sodium fluoride. Sodium fluoride is recovered from the aqueous solution and reacted with sulfuric acid to produce hydrogen fluoride.

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