Recovery of high-boiling aldehydes from rhodium-catalyzed hydrof

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568454, C07C 4578, C07C 4580

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active

051381010

ABSTRACT:
Disclosed is an extraction process for the recovery of high-boiling aldehydes produced by the rhodium-catalyzed hydroformylation of olefins in the presence of a hydroformylation solvent. The extraction process involves intimately contacting a hydroformylation product solution comprising (i) a high-boiling aldehyde, (ii) hydroformylation catalyst components comprising rhodium and an organophosphine compound, and (iii) a hydroformylation solvent with an extraction solution comprising a primary alkanol and water to form a 2-phase mixture. The phases are separated to obtain a hydroformylation solvent phase containing catalyst components and an alkanol/water phase containing the high-boiling aldehyde.

REFERENCES:
patent: 3896047 (1975-07-01), Aycock et al.
patent: 4678857 (1987-07-01), Dureanleau et al.
patent: 4845306 (1989-07-01), Puckette

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