Recovery of bismuth from chloride process solutions

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group ib metal

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423 87, C01G 2900

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042859123

ABSTRACT:
A method for the separation of bismuth from a complex chloride solution obtained by leaching with chloride reagents ores containing bismuth and high concentrations of other metals comprising adding to said complex chloride solution at least a stoichiometric amount of a precipitating agent selected from the group consisting of hexamminecobalt (III) salts and hexamminechromium (III) salts soluble in said solution to precipitate said bismuth as a hexamminecobalt (III) bismuth salt or a hexamminechromium (III) bismuth salt and separating said precipitate from said solution.

REFERENCES:
Ephraim, Inorganic Chemistry, Sixth Edition, (1954), Interscience Publishers, Inc., pp. 335-337.

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