Recovery of anhydrous zinc chloride

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group iib metal

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423101, 423491, 423DIG14, 204 66, C01G 904

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active

046311769

ABSTRACT:
A process for the recovery of anhydrous zinc chloride from aqueous solutions containing zinc chloride and typical impurities, comprising: extracting zinc chloride onto a suitable organic extractant such as TBP; stripping the organic extractant with an organic reagent immiscible in the extractant, such as ethylene glycol; adding ammonia or other ammine donor to the loaded organic strip to precipitate a zinc chloride-ammine composition which may be decomposed to anhydrous zinc chloride by heating. The anhydrous zinc chloride is of high purity suitable for fused salt electrolysis to produce elemental zinc.

REFERENCES:
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patent: 3446720 (1969-05-01), Brooks
patent: 3673061 (1972-06-01), Kruesi
U.S. Bureau of Mines publication RI 8524, (1981).
Gmelins Handbuch der Anorganischen Chemie, Zink Achte Auflage, Verlag Chemie, (1956) pp. 871-875.
Nogueira, E. D., et al., "Winning Zinc Through Solvent Extraction and Electrowinning," E&MJ, 92-94 (Oct., 1979).
Thomas, B. K., et al., "Leaching of Oxidic Zinc Materials with Chlorine and Chlorine Hydrate," Metallurgical Transactions B, 12B:281-285 (Jun. 1981).
Forrest, V. M. P., et al., "The Extraction of Zinc and Cadmium by Tri-N-Butyl Phosphate from Aqueous Chloride Solutions," J.Inorg. Chem., 31:187-197 (1969).
May, J. T., et al., "Dehydrating Magnesium Chloride by Double-Salt Decomposition," Bureau of Mines Report of Investigations 8277, pp. 1-19.
Allain, R. J., "A New Economic Process for Making Anhydrous Magnesium Chloride," TMS-AIME, p. 325 (Feb. 24-28, 1980).

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