Recovery of aluminum from spent liquor

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group iiia metal or beryllium

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423122, 423127, 423130, 423181, 423185, 423186, C01F 106, C01D 134

Patent

active

045812071

ABSTRACT:
A process for the purification of spent liquor from an alumina precipitation stage is disclosed wherein the spent liquor is first contacted with 50 volume % or less ethanol to form a sodium oxalate precipitate and the, after removal of the sodium oxalate precipitate is contacted with over 50 volume % of ethanol extraction fluid to separate the mixture into a first layer comprising the ethanol and at least a portion of the caustic from the spent liquor and a second layer which comprises the remainder of the spent liquor. The spent liquor may then be subjected to a further precipitation to recover further alumina. The spent liquor remaining may be further treated in subsequent extraction steps to concentrate and dispose of undesirable impurities remaining.

REFERENCES:
patent: 2806766 (1957-09-01), Anderson
patent: 3511606 (1970-05-01), Haliff et al.
patent: 4172879 (1979-10-01), Miller et al.
patent: 4275042 (1981-06-01), Leuer
patent: 4430310 (1984-02-01), Malito et al.
patent: 4464347 (1984-08-01), Bush

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