Recovery of alkali values from sodium bicarbonate-containing ore

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Alkali metal

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423421, 423425, 423427, 23302T, 299 5, C22B 2610, C01D 700, E21C 4108

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active

042833728

ABSTRACT:
A method for recovering alkali value from sodium bicarbonate-containing ore by utilizing an aqueous solvent containing ammonia. The aqueous ammonia solvent is contacted with the ore to solubilize the sodium bicarbonate-containing ore. The alkali values in the resulting solution are crystallized, preferably as sodium carbonate monohydrate or as sodium sesquicarbonate, which may be processed to recover soda ash. Aqueous ammonia solvent is preferably regenerated from the mother liquor remaining after recovery of the solids, the ammonia solvent then being employed in a cyclic method to recover additional alkali values from the ore.

REFERENCES:
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patent: 1980691 (1934-11-01), MacMullin
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patent: 3953073 (1976-04-01), Kube
Thorpe's Dictionary of Applied Chemistry, Longmans, Green and Co. London 1950 vol. X pp. 819-824, 842-843.
Hackh's Chemical Dictionary The Blakiston Co., New York 1953 pp. 46 and 31.

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