Reagent and kit for determining isoprenylating activity and inhi

Chemistry: natural resins or derivatives; peptides or proteins; – Proteins – i.e. – more than 100 amino acid residues – Blood proteins or globulins – e.g. – proteoglycans – platelet...

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530810, 530811, 530812, 530813, 530814, 435 71, 435975, C01K 1600, G01N 3353

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active

059524731

ABSTRACT:
The invention provides an immobilised oligopeptide for detecting protein prenylation consisting of an oligopeptide containing the amino acid sequence Xad-Xac-Xab-Xaa-OH at its carboxyl-terminus, at least one of Xaa, Xab, Xac and Xad representing cysteine (Cys), said sequence being capable of acting as a substrate for a prenyl transferase catalysing protein prenylation, and being bonded to a solid carrier, preferably at its amino-terminus. The invention further provides a kit for detecting protein prenylation comprising a first immobilised oligopeptide as mentioned above and a second immobilised oligopeptide which differs from said first immobilised oligopeptide in that the cysteine residue is substituted by another amino acid. Also provided are antibodies against the prenylated oligopeptides.

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"A protein geranylgeranyltransferase from bovine brain: Implications for protein prenylation specificity", Proceedings of the National Academy of Sciences of USA, vol. 88, Jun. 1991, Washington by K. Yokoyama et al., pp. 5302-5306.
"In vitro identification of a soluble protein: geranylgeranyl transferase from rat tissues", The Journal of Biological Chemistry, vol. 266, No. 21, Jul 25, 1991, Baltimore, by A. Joly et al., pp. 13495-13498.
"Sequence dependence of protein isoprenylation", The Journal of Biological Chemistry, vol. 266, No. 22, Aug. 5, 1991, Baltimore by S.L. Moores et al., pp. 14603-14610.
"Nonfarnesylated tetrapeptide inhibitors of protein farnesyltransferase", The Journal of Biological Chemistry, vol. 266, No. 24, Aug. 25, 1991, Baltimore, by J.L. Goldstein et al., pp. 15575-15578.
"Biochemistry of protein prenylation", Journal of Lipid Research, vol. 33, No. 12, Dec. 1992, Bethesda by P.J. Casey, pp. 1731-1740.

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