Reactive modifier of elastomeric comb copolymer for thermosettin

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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5263171, 526319, 526320, 526328, 5263285, 5263295, 5263296, 5263297, 526329, 5263291, 5263294, 5263292, C08F22028, C08F22006, C08F22000

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active

055063209

ABSTRACT:
A reactive polymeric modifier to improve toughness and/or flexibility of thermosetting resins where the polymer has a comb configuration including a saturated polymeric backbone having reactive groups at each end and at least one pendent chain which is miscible with the thermosetting resin while it is uncured; the backbone being a polymeric chain of carbon-carbon linkages free of olefinic unsaturation, having a glass transition temperature Tg in the range from -100.degree. C. to 25.degree. C.;
the reactive groups being reactive with the thermosetting resin, being positioned on both ends of the backbone, and comprising, on average, at least 1.2 but less than 2 reactive groups positioned so as to yield a substantially difunctionalized comb;
the pendent chain or chains being linked to said backbone, being present in an amount in the range from 3% to 40% by weight of said comb copolymer, and having from 2 to 250 repeating units selected from the group consisting of polyester, polyether, polystyrene, and polymethacrylate; and,
the comb polymer having a number average molecular weight in the range from 1,000 to 20,000, and a process for making the modifier.

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