Reactive compounds containing perfluorocyclobutane rings

Organic compounds -- part of the class 532-570 series – Organic compounds – Esters having the thiocarboxylate group – -cx- – wherein the...

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5262924, 526293, 526294, 526242, 568699, 568839, C07C32704, C07C 3504, C08F 1802, C08F 1220

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052102653

ABSTRACT:
Novel compounds have at least one perfluorocyclobutane ring and at least two functional groups suitable for forming condensation polymers. Preferably the compounds have a structures represented by Formula II: ##STR1## wherein R and R' independently represent optionally inertly substituted groups: X and X' represent any molecular structures which link R and R' with the perfluorocyclobutane ring; n and n' are the number of G and G' groups, respectively: and G and G' independently represent any reactive functional groups or any groups convertible into reactive functional groups. The compounds are preferably prepared by a process of thermally dimerizing trifluorovinyl compound to form a compounds of Formula I

REFERENCES:
patent: 2404374 (1946-07-01), Harmon
patent: 2671799 (1954-03-01), Miller
patent: 2848504 (1958-08-01), Dixon
patent: 2922823 (1960-01-01), Tarrant
patent: 2958685 (1960-11-01), Eleuterio
patent: 2982786 (1961-05-01), McCane
patent: 3022356 (1962-02-01), Nooy
patent: 3111509 (1963-11-01), Folt
patent: 3114778 (1963-12-01), Fritz et al.
patent: 3277068 (1966-10-01), Wall et al.
patent: 3303145 (1967-02-01), Carlson
patent: 3310606 (1967-03-01), Fritz
patent: 3316312 (1967-04-01), McCane et al.
patent: 3505411 (1970-04-01), Rice
patent: 3549606 (1970-12-01), Gash
patent: 3682876 (1972-10-01), Anderson et al.
patent: 3696154 (1972-10-01), Anderson
patent: 3840603 (1974-10-01), Anderson et al.
patent: 3900380 (1975-08-01), Anderson et al.
patent: 3926989 (1975-12-01), Rebsdat et al.
patent: 4154753 (1979-05-01), Fielding
patent: 4377711 (1983-03-01), Rico et al.
patent: 4423249 (1983-12-01), Carl et al.
patent: 5021602 (1991-06-01), Clement et al.
patent: 5037917 (1991-08-01), Babb et al.
patent: 5037918 (1991-08-01), Babb
patent: 5037919 (1991-08-01), Clement et al.
patent: 5066746 (1991-11-01), Clement et al.
U.S. application Ser. No. 364,667 filed Jun. 9, 1989.
U.S. application Ser. No. 534,819 filed Jun. 7, 1990.
U.S. application Ser. No. 364,666 filed Jun. 9, 1989.
U.S. application Ser. No. 364,686 filed Jun. 9, 1989.
U.S. application Ser. No. 364,665 filed Jun. 9, 1989.
U.S. application Ser. No. 451,404 filed Dec. 15, 1989.
U.S. application Ser. No. 673,882 filed Mar. 22, 1991.
U.S. application Ser. No. 668,294 filed Mar. 12, 1991.
U.S. application Ser. No. 668,296 filed Mar. 12, 1991.
U.S. application Ser. No. 673,884 filed Mar. 22, 1991.
U.S. application Ser. No. 625,588 filed Dec. 10, 1990.
Chemical Abstract 59:8879c.
Chemical Abstract 77:34091k.
Chemical Abstract 105:171569h.
Chemical Abstract 110:181626.
Coffman, Barrick, Cramer and Raasch in J. Amer. Chem. Soc. vol. 71 (1949) pp. 490-496, "Synthesis of Tetrafluoro Cyclobutanes by Cycloalkylation".
Henne and Ruh in J. Amer. Chem. Soc., 69, 279-281 (1947).
Maurice Prober in J. Amer. Chem. Soc., 75, 968-973 (1953).
Hauptschein et al. in J. Amer. Chem. Soc., 79 2549-2553 (1957).
Miller et al. in J. Amer. Chem. Soc., 83, 1767-1768 (1961).
Brown et al. in J. Poly. Sci. Part A-1, vol. 3, (1965) pp. 1641-1660.
Brown et al. in J. Poly. Sci. Part A-1, vol. 34 (1966) pp. 131-1140.
Banks, et al. in J. Chem. Soc. (C), 22 (1966) pp. 2051-2052.
Sharkey in Fluorine Chem. Rev. 2, 1-53 (1968).
Crawford in J. Chem. Soc. (C), 1967 pp. 2395-2396.
Hodgdon and MacDonald in J. Poly. Sci. Part A-1, vol. 6, (1968) pp. 711-717.
Chambers in Fluorine in Organic Chemistry, John Wiley, New York, (1973) pp. 173-191 and 199-208.
Rico and Waselman in J. Fluorine Chemistry, 20 (1982) pp. 759-764.
Heinze and Burton in J. Org. Chem. 1988, 53, pp. 2714-2720.
Paleta et al. "Haloacrylic acids VI. Ethylene glycol bis(trifluoroacrylate) Sb. Vsy. Sk. Chem.-Technol." 1976, C23, 5-11 (1976).
A. A. Glazkov et al., "Cycloaddition of Perfluorovinyl Ethers to Dienes," Bulletin of the Academy of Sciences of the USSR.
P. Tarrant et al., The Preparation and Reactions of some Silanes containing the Trifluorovinyl group, J. Org. Chem. vol. 31, No. 4, Apr. 1966, pp. 1143-1146.
Drysdale, Gilbert, Sinclair and Sharkey J. Amer. Chem. Soc. vol. 80 (1958) pp. 3672-3675.
McBee, Hsu, Pierce and Roberts in "Diels-Alder Reactions with Fluorine-Containing Olefins" in J. Amer. Chem. Soc., vol. 77 (1955) pp. 915-917.
Chambon and Winter in J. of Rheology 31 (1987) pp. 683-697.
Perry in Fluorine Chemistry Reviews 1 (2) (1967) pp. 253-313.
Nijenhuis and Winter in Macromolecules 22 (1989) pp. 411-414.
Winter and Chambon in J. of Rheology, 30(2) (1986) pp. 367-382.

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