Reactive acrylic oligomer, grafted acrylic resinous composition

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525293, 525301, 525267, 525910, C08F27102, C08F29112, C08F26504

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active

046597816

ABSTRACT:
The present invention provides a reactive acrylic oligomer obtained by the method of polymerizing at least one .alpha., .beta.-ethylenically unsaturated monomers having no oxirane ring and/or carboxyl groups, in an organic solvent and in the presence of azo initiator having carboxyl group and tertiary amine, and then reacting the same with a compound having .alpha., .beta.-ethylenically unsaturated bonding and oxirane ring. The invention further provides a grafted acrylic resinous composition obtained by the method of copolymerizing said reactive acrylic oligomer with at least one .alpha., .beta.-ethylenically unsaturated monomers which will constitute the backbone of the graft polymer, as well as the coating composition containing as resinous vehicle the abovesaid resinous composition and especially the resinous composition whose graft polymer is an amphoteric acrylic resin having backbone chain with acidic groups and branched chains with concentrated quantity of basic groups.

REFERENCES:
patent: 3285949 (1966-11-01), Siebert
patent: 3390206 (1968-06-01), Thompson et al.
patent: 3514500 (1970-05-01), Osmond et al.
patent: 4013710 (1977-03-01), Skillicorn
patent: 4085168 (1978-04-01), Milkovich et al.
patent: 4554324 (1985-11-01), Husman et al.

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