Reactivation of spent chromia-alumina catalyst by zinc oxide dop

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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252411R, 252416, 252465, B01J 2120, B01J 2392

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active

043127800

ABSTRACT:
A method for the reactivation of aged chromia-alumina dehydrogenation catalyst which involves doping the aged catalyst with minor amounts of zinc oxide, preferrably in the range of about 0.35% zinc oxide to 1.35% zinc oxide on the catalyst. The zinc oxide is added to the aged catalyst preferrably by impregnation by immersion or spraying of a zinc nitrate solution, followed by drying and heat treating. Alternatively the zinc oxide addition can be accomplished by use of a volatile organic zinc compound added to the saturated feedstock and subsequent air regeneration of the catalyst in situ without removal of the catalyst from the reactor.

REFERENCES:
patent: 2265641 (1941-12-01), Grosskinsky et al.
patent: 2375402 (1945-05-01), Corson et al.
patent: 2382394 (1945-08-01), Bremner et al.
patent: 2395875 (1946-03-01), Kearby
patent: 2901419 (1959-08-01), Brill

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